2021
Observation of a potential-dependent switch of water-oxidation mechanism on Co-oxide-based catalysts
Lang C, Li J, Yang K, Wang Y, He D, Thorne J, Croslow S, Dong Q, Zhao Y, Prostko G, Brudvig G, Batista V, Waegele M, Wang D. Observation of a potential-dependent switch of water-oxidation mechanism on Co-oxide-based catalysts. Chem 2021, 7: 2101-2117. DOI: 10.1016/j.chempr.2021.03.015.Peer-Reviewed Original ResearchWater oxidation mechanismWater oxidation reactionWater nucleophilic attack mechanismCo-based catalystsO bond formationNucleophilic attack mechanismKey elementary stepsHeterogeneous catalystsSalt electrolyteElectrode potentialApplied potentialBond formationLow driving forceO couplingElementary stepsMechanistic switchCatalystHigh driving forceDriving forceReactionAttack mechanismWater activityElectrolyteHereinPotential
1999
Femtosecond photoelectron spectroscopy of the I2− anion: Characterization of the Ã′ 2Πg,1/2 excited state
Zanni M, Batista V, Greenblatt B, Miller W, Neumark D. Femtosecond photoelectron spectroscopy of the I2− anion: Characterization of the Ã′ 2Πg,1/2 excited state. The Journal Of Chemical Physics 1999, 110: 3748-3755. DOI: 10.1063/1.478264.Peer-Reviewed Original ResearchFemtosecond photoelectron spectroscopyEquilibrium bond lengthPhotoelectron spectroscopyBond lengthsWell depthPotential energy curvesUpper state potentialRepulsive potential wallExcited statesEnergy curvesState potentialPotential wallSemiempirical resultsSpectroscopyMorse potentialAnionsAttractive portionStateSpectraPotential