2024
Dehydrogenation and Transfer Hydrogenation of Alkenones to Phenols and Ketones on Carbon-Supported Noble Metals
Li K, Kelly H, Franco A, Batista V, Baráth E. Dehydrogenation and Transfer Hydrogenation of Alkenones to Phenols and Ketones on Carbon-Supported Noble Metals. ACS Catalysis 2024, 14: 2883-2896. PMID: 38449532, PMCID: PMC10913045, DOI: 10.1021/acscatal.3c04849.Peer-Reviewed Original ResearchKeto-enol tautomerismCatalytic materialsPresence of hydrogen donorsSelection of catalytic materialsSaturated cyclic ketonesM-O bondsNoble metal catalystsBond distance changesAromatic compoundsEntropy of activationBalance of enthalpyTransfer hydrogenationCyclic ketonesMetal catalystsCatalytic dehydrogenationDienolate intermediateDehydrogenation reactionM-OCyclic alcoholsNoble metalsCatalytic activityHydrogen donorBinding orientationEnonesTautomerism
2012
Fuel selection for a regenerative organic fuel cell/flow battery: thermodynamic considerations
Araujo C, Simone D, Konezny S, Shim A, Crabtree R, Soloveichik G, Batista V. Fuel selection for a regenerative organic fuel cell/flow battery: thermodynamic considerations. Energy & Environmental Science 2012, 5: 9534-9542. DOI: 10.1039/c2ee22749e.Peer-Reviewed Original ResearchOpen circuit potentialTheoretical open circuit potentialHydrogen fuel cellsThermodynamic considerationsFlow batteriesDehydrogenation productsDehydrogenation reactionFuel cellsOrganic fuelsCircuit potentialOrganic carriersBattery systemEnergy densityHeterocyclicHydrogenationCarbocyclicBatteriesReactionHydrocarbonsFuel