2014
Electrochemical Reduction of Aqueous Imidazolium on Pt(111) by Proton Coupled Electron Transfer
Liao K, Askerka M, Zeitler E, Bocarsly A, Batista V. Electrochemical Reduction of Aqueous Imidazolium on Pt(111) by Proton Coupled Electron Transfer. Topics In Catalysis 2014, 58: 23-29. DOI: 10.1007/s11244-014-0340-2.Peer-Reviewed Original ResearchOne-electron shuttleElectron transferCO2 reductionReaction mechanismVoltammetric half-wave potentialAqueous CO2 reductionRecent electrochemical studiesOne-electron reductionHalf-wave potentialHydride transfer mechanismUnderlying reaction mechanismPotential of caAqueous ImidazoliumElectrochemical reductionMultielectron reductionElectrochemical studiesElectrochemical behaviorCathodic wavePt surfacePyridine solutionBrønsted acidsDFT studyFormic acidPyridiniumSuch reactions
2012
Synthesis and computational studies of Mg complexes supported by 2,2′:6,2′′-terpyridine ligands
Guard LM, Palma JL, Stratton WP, Allen LJ, Brudvig GW, Crabtree RH, Batista VS, Hazari N. Synthesis and computational studies of Mg complexes supported by 2,2′:6,2′′-terpyridine ligands. Dalton Transactions 2012, 41: 8098-8110. PMID: 22430933, DOI: 10.1039/c2dt12426b.Peer-Reviewed Original ResearchGrignard reagentsTerpyridine ligandTridentate nitrogen ligandsDiethyl etherX-ray crystallographyDialkyl speciesTerpy ligandFree terpyridinesNitrogen ligandsAlkyl complexesAlkyl speciesCoordination planeNitrogen donorsDFT studySteric bulkTerpyridineCompounds 5aReaction conditionsMg complexesSimilar reactionComputational studyOnly productLigandsMixed halidesReagents