2021
Charge Stabilization in Axially Linked Donor – Aluminum(III) Porphyrin – Fullerene Reaction Center Models
Zarrabi N, Seetharaman S, Chaudhuri S, Holzer N, Batista V, van der Est A, D'Souza F, Poddutoori P. Charge Stabilization in Axially Linked Donor – Aluminum(III) Porphyrin – Fullerene Reaction Center Models. ECS Meeting Abstracts 2021, MA2021-01: 781-781. DOI: 10.1149/ma2021-0116781mtgabs.Peer-Reviewed Original ResearchCharge-separated stateFinal charge-separated stateReaction center modelsRedox potentialRadical pairSequential electron transferSubstitution of phenylCoordination bondsMeso positionsPentafluorophenyl groupsDonor unitsElectron transferCharge stabilizationPorphyrin planeTriad resultsC60Ground stateTrifluorophenylCovalentPorphyrinsRedoxPhenylBondsAcceptorDonors
2017
Linker Length-Dependent Electron-Injection Dynamics of Trimesitylporphyrins on SnO2 Films
Lee S, Regan K, Hedström S, Matula A, Chaudhuri S, Crabtree R, Batista V, Schmuttenmaer C, Brudvig G. Linker Length-Dependent Electron-Injection Dynamics of Trimesitylporphyrins on SnO2 Films. The Journal Of Physical Chemistry C 2017, 121: 22690-22699. DOI: 10.1021/acs.jpcc.7b07855.Peer-Reviewed Original ResearchDye-sensitized photoelectrochemical cellsElectron injection dynamicsPhotoelectrochemical cellsLinker lengthMetal oxide filmsMolecular photosensitizersPorphyrin coreAnchor groupsElectron acceptorInjection dynamicsLinkerSnO2 filmsOxide filmsFilmsTerphenyleneSystematic studyPhenylenePorphyrinsBiphenyleneSpectroscopyComputational modelingAcceptorPhotosensitizerSynthesisOxide