Long-range electrostatic effects from intramolecular Lewis acid binding influence the redox properties of cobalt–porphyrin complexes
Alvarez-Hernandez J, Zhang X, Cui K, Deziel A, Hammes-Schiffer S, Hazari N, Piekut N, Zhong M. Long-range electrostatic effects from intramolecular Lewis acid binding influence the redox properties of cobalt–porphyrin complexes. Chemical Science 2024, 15: 6800-6815. PMID: 38725508, PMCID: PMC11077573, DOI: 10.1039/d3sc06177a.Peer-Reviewed Original ResearchAza-crown ethersLewis acidAnodic shiftPorphyrin complexesRedox propertiesLong-range electrostatic effectsDensity functional theory calculationsElectrostatic effectsLewis acid bindingCobalt porphyrin complexesMetal aqua complexesPrimary coordination sphereCo II ionsFunctional theory calculationsCoordination sphereReduction electrocatalystsLi +NMR spectroscopyEther groupsCompounds 1Theory calculationsRedox chemistryII ionsBinding constantsReduction potential