2020
Synthesis of organometallic pincer-supported cobalt(II) complexes
Townsend T, Bernskoetter W, Brudvig G, Hazari N, Lant H, Mercado B. Synthesis of organometallic pincer-supported cobalt(II) complexes. Polyhedron 2020, 177: 114308. DOI: 10.1016/j.poly.2019.114308.Peer-Reviewed Original Research
2019
Synthesis and Reactivity of Paramagnetic Nickel Polypyridyl Complexes Relevant to C(sp2)–C(sp3)Coupling Reactions
Beromi M, Brudvig G, Hazari N, Lant H, Mercado B. Synthesis and Reactivity of Paramagnetic Nickel Polypyridyl Complexes Relevant to C(sp2)–C(sp3)Coupling Reactions. Angewandte Chemie 2019, 131: 6155-6159. DOI: 10.1002/ange.201901866.Peer-Reviewed Original ResearchModification of a pyridine-alkoxide ligand during the synthesis of coordination compounds
Shopov D, Sharninghausen L, Sinha S, Mercado B, Brudvig G, Crabtree R. Modification of a pyridine-alkoxide ligand during the synthesis of coordination compounds. Inorganica Chimica Acta 2019, 484: 75-78. DOI: 10.1016/j.ica.2018.09.020.Peer-Reviewed Original ResearchPyridine-alkoxide ligandsWater oxidation catalysisHigher oxidation statesCoordination compoundsPincer ligandGeminal methyl groupsCatalytic conditionsOxidation stateOxidation catalystReaction conditionsMinor byproductsAliphatic alkenesMinor productsOxidative conditionsMethyl groupN-oxideLigandsBlue solutionCH groupPincerStructural analoguesSynthesisComplexesCatalystCentral unit
2017
Linker Length-Dependent Electron-Injection Dynamics of Trimesitylporphyrins on SnO2 Films
Lee S, Regan K, Hedström S, Matula A, Chaudhuri S, Crabtree R, Batista V, Schmuttenmaer C, Brudvig G. Linker Length-Dependent Electron-Injection Dynamics of Trimesitylporphyrins on SnO2 Films. The Journal Of Physical Chemistry C 2017, 121: 22690-22699. DOI: 10.1021/acs.jpcc.7b07855.Peer-Reviewed Original ResearchDye-sensitized photoelectrochemical cellsElectron injection dynamicsPhotoelectrochemical cellsLinker lengthMetal oxide filmsMolecular photosensitizersPorphyrin coreAnchor groupsElectron acceptorInjection dynamicsLinkerSnO2 filmsOxide filmsFilmsTerphenyleneSystematic studyPhenylenePorphyrinsBiphenyleneSpectroscopyComputational modelingAcceptorPhotosensitizerSynthesisOxideSynthesis and Characterization of Iridium(V) Coordination Complexes With an N,O‐Donor Organic Ligand
Sharninghausen L, Sinha S, Shopov D, Mercado B, Balcells D, Brudvig G, Crabtree R. Synthesis and Characterization of Iridium(V) Coordination Complexes With an N,O‐Donor Organic Ligand. Angewandte Chemie 2017, 129: 13227-13231. DOI: 10.1002/ange.201707593.Peer-Reviewed Original ResearchCoordination complexesO-donor organic ligandsMononuclear coordination complexesO-donor environmentMetal-centered oxidationX-ray crystallographyOrganic ligandsDonor strengthAlkoxide groupsDFT calculationsD orbitalsUnprecedented stabilityComplexesLigandsOxidationIR-VIsomersXPSCrystallographyV complexSynthesisCharacterizationStabilityCalculationsDegradationSynthesis of pyridine-alkoxide ligands for formation of polynuclear complexes
Shopov D, Sharninghausen L, Sinha S, Borowski J, Mercado B, Brudvig G, Crabtree R. Synthesis of pyridine-alkoxide ligands for formation of polynuclear complexes. New Journal Of Chemistry 2017, 41: 6709-6719. DOI: 10.1039/c7nj01845b.Peer-Reviewed Original ResearchO-donor ligandsPolynuclear complexesFirst-row transition metalsPyridine-alkoxide ligandsInexpensive starting materialsOne-step synthesisX-ray crystallographyPolynuclear clustersTransition metalsStarting materialScalable procedureGeneral formulaLigandsEffective bindingLarge-scale productionLigand 2Chelation powerComplexesSynthesisDenticityCluster formationDeprotonationFormationCrystallographyChromatography
2013
Synthesis and Properties of NHC-Supported Palladium(I) Dimers with Bridging Allyl, Cyclopentadienyl, and Indenyl Ligands
Dai W, Chalkley M, Brudvig G, Hazari N, Melvin P, Pokhrel R, Takase M. Synthesis and Properties of NHC-Supported Palladium(I) Dimers with Bridging Allyl, Cyclopentadienyl, and Indenyl Ligands. Organometallics 2013, 32: 5114-5127. DOI: 10.1021/om400687m.Peer-Reviewed Original Research
2002
Two New Terpyridine Dimanganese Complexes: A Manganese(III,III) Complex with a Single Unsupported Oxo Bridge and a Manganese(III,IV) Complex with a Dioxo Bridge. Synthesis, Structure, and Redox Properties
Baffert C, Collomb M, Deronzier A, Pécaut J, Limburg J, Crabtree R, Brudvig G. Two New Terpyridine Dimanganese Complexes: A Manganese(III,III) Complex with a Single Unsupported Oxo Bridge and a Manganese(III,IV) Complex with a Dioxo Bridge. Synthesis, Structure, and Redox Properties. Inorganic Chemistry 2002, 41: 1404-1411. PMID: 11896708, DOI: 10.1021/ic0107375.Peer-Reviewed Original ResearchConceptsOxo bridgeElectrochemical behaviorX-ray structureMononuclear complexesComplexes 4Oxo complexesRedox propertiesAqua complexesDimanganese complexesOrganic mediaTrans complexesCis geometrySolid stateDioxo bridgeTrans geometryCis complexesDisproportionation processTrans configurationCrystallographic formsComplexesMn atomsCisMonooxoLigandsSynthesis
1998
Synthesis and characterization of an internal emission standard and applications to fluorescence studies of photosystem II
Schweitzer R, Brudvig G. Synthesis and characterization of an internal emission standard and applications to fluorescence studies of photosystem II. Biopolymers 1998, 2: 167-171. DOI: 10.1002/(sici)1520-6343(1996)2:3<167::aid-bspy3>3.0.co;2-5.Peer-Reviewed Original ResearchChelate complexesFluorescence intensityFluorescence measurementsDiethylenetriaminepentaacetic acid derivativeTerbium luminescenceAqueous phaseTerbium emissionAcid derivativesPyrimidine ringComplexesPhotosystem II functionLow temperaturePhotosynthetic organismsLow absorptionCryogenic temperaturesLanthanidesDifferent samplesLigandsSynthesisLuminescenceTerbiumTemperatureDerivativesPurificationEmission standards
1988
ChemInform Abstract: Modeling the Oxygen‐Evolving Center of Photosystem II: Synthesis and Characterization of a Tetranuclear Manganese Carboxylate Complex.
KULAWIEC R, CRABTREE R, BRUDVIG G, SCHULTE G. ChemInform Abstract: Modeling the Oxygen‐Evolving Center of Photosystem II: Synthesis and Characterization of a Tetranuclear Manganese Carboxylate Complex. ChemInform 1988, 19: no-no. DOI: 10.1002/chin.198832235.Peer-Reviewed Original Research