1999
A Functional Model for O-O Bond Formation by the O2-Evolving Complex in Photosystem II
Limburg J, Vrettos J, Liable-Sands L, Rheingold A, Crabtree R, Brudvig G. A Functional Model for O-O Bond Formation by the O2-Evolving Complex in Photosystem II. Science 1999, 283: 1524-1527. PMID: 10066173, DOI: 10.1126/science.283.5407.1524.Peer-Reviewed Original ResearchConceptsMolecular oxygenPhotosystem IIO bond formationPhotosynthetic water oxidationWater oxidationManganese dimerBond formationOxygen atomsActive siteIsotope labelingManganese ionsOxygenPhotosynthesisWaterSodium hypochloriteOxidationIonsFormationAtomsDimersComplexesO2Functional modelConversionHypochlorite
1998
A Structural and Mechanistic Model of the O2-Evolving Complex of Photosystem II
Szalai V, Stone D, Brudvig G. A Structural and Mechanistic Model of the O2-Evolving Complex of Photosystem II. 1998, 1403-1406. DOI: 10.1007/978-94-011-3953-3_331.Peer-Reviewed Original ResearchElectron paramagnetic resonanceMn4 clusterO bond-forming stepReactivity of MnBond-forming stepWater oxidation siteWater/hydroxidePhotosystem II membranesPoint-dipole approximationMN4 complexesElectron transferO speciesParamagnetic resonanceEPR signalS2 stateSpectral simulationsPhotosystem IIYZComplexesMn atomsStructural modelCluster orientationChemistryHydroxideAtoms
1992
Calcium binding site(s) of Photosystem II as probed by lanthanides
Bakou A, Buser C, Dandulakis G, Brudvig G, Ghanotakis D. Calcium binding site(s) of Photosystem II as probed by lanthanides. Biochimica Et Biophysica Acta (BBA) - Bioenergetics 1992, 1099: 131-136. DOI: 10.1016/0005-2728(92)90209-k.Peer-Reviewed Original Research