2020
Synthesis of organometallic pincer-supported cobalt(II) complexes
Townsend T, Bernskoetter W, Brudvig G, Hazari N, Lant H, Mercado B. Synthesis of organometallic pincer-supported cobalt(II) complexes. Polyhedron 2020, 177: 114308. DOI: 10.1016/j.poly.2019.114308.Peer-Reviewed Original Research
2019
Synthesis and Reactivity of Paramagnetic Nickel Polypyridyl Complexes Relevant to C(sp2)–C(sp3)Coupling Reactions
Beromi M, Brudvig G, Hazari N, Lant H, Mercado B. Synthesis and Reactivity of Paramagnetic Nickel Polypyridyl Complexes Relevant to C(sp2)–C(sp3)Coupling Reactions. Angewandte Chemie 2019, 131: 6155-6159. DOI: 10.1002/ange.201901866.Peer-Reviewed Original Research
2015
Comparison of dppf‐Supported Nickel Precatalysts for the Suzuki–Miyaura Reaction: The Observation and Activity of Nickel(I)
Guard L, Beromi M, Brudvig G, Hazari N, Vinyard D. Comparison of dppf‐Supported Nickel Precatalysts for the Suzuki–Miyaura Reaction: The Observation and Activity of Nickel(I). Angewandte Chemie 2015, 127: 13550-13554. DOI: 10.1002/ange.201505699.Peer-Reviewed Original ResearchSuzuki–Miyaura reactionNi II complexesSimilar catalytic activityDppf ligandNickel precatalystsNi precatalystsOxidation stateCatalytic activityPrecatalystHeterocyclic substratesNi 0Potential chemicalI speciesReactionII complexesRoom temperaturePd systemLigandsComplexesChemicalsNiSignificant amountSubstrate
2005
General Synthesis of Di-μ-oxo Dimanganese Complexes as Functional Models for the Oxygen Evolving Complex of Photosystem II
Chen H, Tagore R, Das S, Incarvito C, Faller J, Crabtree R, Brudvig G. General Synthesis of Di-μ-oxo Dimanganese Complexes as Functional Models for the Oxygen Evolving Complex of Photosystem II. Inorganic Chemistry 2005, 44: 7661-7670. PMID: 16212393, DOI: 10.1021/ic0509940.Peer-Reviewed Original ResearchConceptsDimanganese complexesCatalytic activitySeries of complexesGeneral preparative methodUV-visible spectroscopyElectrospray mass spectrometryOxygen-Evolving ComplexX-ray crystallographyPhotosystem IIParent complexEPR spectroscopyOxygen-evolving activityGeneral synthesisPreparative methodLigand librariesMass spectrometryHigh product purityComplexesMn dimersSpectroscopyProduct purityPrecursorsTerpyCrystallographyOxo