Selective Heterogeneous Transfer Hydrogenation from Tertiary Amines to Alkynes
Roeder G, Kelly H, Yang G, Bauer T, Haller G, Batista V, Baráth E. Selective Heterogeneous Transfer Hydrogenation from Tertiary Amines to Alkynes. ACS Catalysis 2021, 11: 5405-5415. DOI: 10.1021/acscatal.0c05186.Peer-Reviewed Original ResearchPt/CPd/CTertiary aminesHydrogenation mechanismDensity functional theory calculationsTransfer hydrogenation reactionHydrogen transfer reactionsNoble metal surfacesFunctional theory calculationsTransfer hydrogenation mechanismHigh rate constantsAmine partnersHydrogenation reactionsTransfer hydrogenationCis selectivityNoble metalsH-donorN-diisopropylethylamineTransfer reactionsSurface coverageTheory calculationsAlkynesMetal surfaceSubstituted alkanesInert conditions