Dehydrogenation and Transfer Hydrogenation of Alkenones to Phenols and Ketones on Carbon-Supported Noble Metals
Li K, Kelly H, Franco A, Batista V, Baráth E. Dehydrogenation and Transfer Hydrogenation of Alkenones to Phenols and Ketones on Carbon-Supported Noble Metals. ACS Catalysis 2024, 14: 2883-2896. PMID: 38449532, PMCID: PMC10913045, DOI: 10.1021/acscatal.3c04849.Peer-Reviewed Original ResearchKeto-enol tautomerismCatalytic materialsPresence of hydrogen donorsSelection of catalytic materialsSaturated cyclic ketonesM-O bondsNoble metal catalystsBond distance changesAromatic compoundsEntropy of activationBalance of enthalpyTransfer hydrogenationCyclic ketonesMetal catalystsCatalytic dehydrogenationDienolate intermediateDehydrogenation reactionM-OCyclic alcoholsNoble metalsCatalytic activityHydrogen donorBinding orientationEnonesTautomerism