Nilay Hazari
John Randolph Huffman Professor of ChemistryDownloadHi-Res Photo
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John Randolph Huffman Professor of Chemistry
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Chemistry
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Research at a Glance
Publications Timeline
A big-picture view of Nilay Hazari's research output by year.
24Publications
142Citations
Publications
2026
Synthesis of Tetrakis(amino)ethylene-Derived Organic Reductants via Thermal Decomposition of Tris(amino)methanes
Kim S, Jia X, Hazari N, Oniani D, Wedal J. Synthesis of Tetrakis(amino)ethylene-Derived Organic Reductants via Thermal Decomposition of Tris(amino)methanes. Organic Letters 2026, 28: 3880-3884. PMID: 41839850, PMCID: PMC13036772, DOI: 10.1021/acs.orglett.6c00699.Peer-Reviewed Original ResearchAltmetricHomogeneous Reductant Facilitated Cross-Electrophile Coupling of Aryl Bromides with NHP Esters
Kundu A, Kim S, Hazari N, Uehling M, Yalla R. Homogeneous Reductant Facilitated Cross-Electrophile Coupling of Aryl Bromides with NHP Esters. Organic Letters 2026, 28: 2518-2523. PMID: 41649964, PMCID: PMC12930507, DOI: 10.1021/acs.orglett.6c00281.Peer-Reviewed Original ResearchCitationsConceptsCross-electrophile couplingNHP estersAryl bromidesCoupling of aryl bromidesCross-electrophile coupling reactionsAlkyl radical generationAryl halidesAryl iodidesAlkyl halidesCoupling reactionAlkyl groupsAlkyl radicalsCarboxylic acidsArylHomogeneous reductionReduction conditionsOrganic reductantsHalidesBromideEsterNon-amidatedRadical generationAlkylationSolventIodideImproving productivity and stability for CO2 hydrogenation by using pincer-ligated Mn complexes with hemilabile ligands
Wedal J, Virtue K, Bernskoetter W, Hazari N, Mercado B, Piekut N. Improving productivity and stability for CO2 hydrogenation by using pincer-ligated Mn complexes with hemilabile ligands. Chem 2026, 102833. DOI: 10.1016/j.chempr.2025.102833.Peer-Reviewed Original ResearchCitationsAltmetricConceptsPincer ligandMn catalystCO2 hydrogenation to formateState-of-the-art catalystsTransition-metal catalystsHydrogenation to formateFirst-row systemsHemilabile coordinationHemilabile ligandsPendant donorsCO2 hydrogenationTurnover frequencyMn complexFirst-rowHemilabileCatalyst lifetimeCatalytic activityCatalystTurnover numberLigandMechanistic studiesPincerDonorHydrogenStability
2025
Unusual Electrochemical Activity of Thin SiO2 Layers Leads to Instability of Molecular Attachment in Hybrid Photoelectrodes
Cappuccino C, Tanwar M, Jia X, Hazari N, Donley C, Fakhraai Z, Manbeck G, Grills D, Polyansky D. Unusual Electrochemical Activity of Thin SiO2 Layers Leads to Instability of Molecular Attachment in Hybrid Photoelectrodes. ACS Applied Energy Materials 2025, 8: 18101-18113. DOI: 10.1021/acsaem.5c03010.Peer-Reviewed Original ResearchConceptsHybrid photoelectrodesSilanol groupsCathodic biasLight-absorbing semiconductorCyclic voltammetry scansElectrochemical lossesCovalently bound moleculesPH-dependent waveHydrophilic silanol groupsCH3CN solutionMolecular catalysisMolecular catalystsElectrochemical stabilitySurface-bound waterArtificial photosynthesisThermal oxidationSiloxane moietyVoltammetry scansPhotoelectrodeOxide layerLayer of silicon oxideLight absorptionOxide surfaceReversible waveChemical stabilityElucidation of Marcus Relationships for Hydride Transfer Reactions Involving Transition Metal Hydrides
Kumar A, Ertem M, Hazari N, Miller A. Elucidation of Marcus Relationships for Hydride Transfer Reactions Involving Transition Metal Hydrides. Journal Of The American Chemical Society 2025, 147: 32671-32688. PMID: 40854557, DOI: 10.1021/jacs.5c08248.Peer-Reviewed Original ResearchCitationsAltmetricConceptsHydride transfer reactionThermodynamic hydricityTransfer reactionsHydride transferThermodynamic driving forceTransition stateMetal hydridesLinear free energy relationshipElectronically different substituentsIr hydride complexP-stacking interactionsTransition metal hydridesFree energy relationshipHydride transfer mechanismRate of hydride transferHydride complexesHydride affinitiesDifferent substituentsMarcus relationshipReorganization energyMarcus theoryMarcus modelEnergy relationshipHydrideRare exampleCatalytic Hydrogenation of a Ruthenium Carbonyl to Formyl Enabled by Metal–Ligand Cooperation
Smith A, Fernández S, Tereniak S, Ahmad S, Kumar A, Chen C, Hazari N, Ertem M, Miller A. Catalytic Hydrogenation of a Ruthenium Carbonyl to Formyl Enabled by Metal–Ligand Cooperation. ACS Catalysis 2025, 15: 13526-13533. DOI: 10.1021/acscatal.5c03137.Peer-Reviewed Original ResearchCitationsAltmetricConceptsMetal-ligand cooperationCatalytic hydrogenationFormyl complexesCarbonyl complexesTransition metal carbonyl complexesLewis acid B(C6F5)3Ruthenium carbonyl complexesMetal carbonyl complexesClasses of catalystsRuthenium carbonylH2 splittingStoichiometric reagentsHydrogenation catalystsRu complexesExternal baseHydride transferMetal ligandsMild conditionsCatalytic routeCatalystFormylationH2 gasRutheniumHydrogenValuable productsPreface to Special Issue “Organometallic Chemistry of CO2”
Adams R, Hazari N. Preface to Special Issue “Organometallic Chemistry of CO2”. Journal Of Organometallic Chemistry 2025, 1034: 123655. DOI: 10.1016/j.jorganchem.2025.123655.Peer-Reviewed Original ResearchNi/Ti Dual Catalyzed Cross-Electrophile Coupling between Unactivated Alkyl Chlorides and Aryl Halides
Oniani D, Jia X, Mane E, Charboneau D, Chow J, Hazari N, Huang H, Lee M, Mercado B, Uehling M, Wedal J. Ni/Ti Dual Catalyzed Cross-Electrophile Coupling between Unactivated Alkyl Chlorides and Aryl Halides. ACS Catalysis 2025, 15: 11726-11738. DOI: 10.1021/acscatal.5c01995.Peer-Reviewed Original ResearchCitationsAltmetricConceptsCross-electrophile couplingUnactivated alkyl chloridesAlkyl chloridesAryl halidesTi catalystAlkyl radicalsTertiary alkyl chloridesSecondary alkyl chloridesStoichiometric experimentsReactive catalystCatalytic cycleNi catalystsCatalystSubstrate classesHalidesArylRare exampleRate of radical productionMechanistic studiesAlkylationChlorideRadicalsInert substrateIntermediateReactionFlash Communication: Ir Complexes with a PhN(CH2CH2PiPr2)2 Pincer Ligand for Reversible CO2 Hydrogenation
Curley J, Hert C, Bernskoetter W, Hazari N, Mercado B, Wedal J. Flash Communication: Ir Complexes with a PhN(CH2CH2PiPr2)2 Pincer Ligand for Reversible CO2 Hydrogenation. Organometallics 2025, 44: 1358-1361. DOI: 10.1021/acs.organomet.5c00153.Peer-Reviewed Original ResearchAltmetricA highly active sulfur based pincer ruthenium catalyst for CO 2 hydrogenation
Mondragón-Díaz A, Kelley S, Hazari N, Bernskoetter W. A highly active sulfur based pincer ruthenium catalyst for CO 2 hydrogenation. Chemical Communications 2025, 61: 6957-6960. PMID: 40230312, DOI: 10.1039/d5cc01194a.Peer-Reviewed Original ResearchCitationsAltmetric
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