2013
Study of an S = 1 Ni II pincer electrocatalyst precursor for aqueous hydrogen production based on paramagnetic 1 H NMR
Luca OR, Konezny SJ, Paulson EK, Habib F, Luthy KM, Murugesu M, Crabtree RH, Batista VS. Study of an S = 1 Ni II pincer electrocatalyst precursor for aqueous hydrogen production based on paramagnetic 1 H NMR. Dalton Transactions 2013, 42: 8802-8807. PMID: 23640289, DOI: 10.1039/c3dt50528f.Peer-Reviewed Original ResearchChemical shiftsTridentate NNN ligandMetal complexesNNN ligandCatalytic applicationsLow overpotentialH NMRAppropriate ligandDFT methodologyAnalogue complexesT1 relaxation rateUnambiguous assignmentHydrogen productionProton environmentNMRH2 productionComplexesLigandsMagnetic susceptibilityRelaxation rateElectrocatalystsOverpotentialReactivityTemperature dependencePrecursors
2012
Organometallic Ni Pincer Complexes for the Electrocatalytic Production of Hydrogen
Luca OR, Blakemore JD, Konezny SJ, Praetorius JM, Schmeier TJ, Hunsinger GB, Batista VS, Brudvig GW, Hazari N, Crabtree RH. Organometallic Ni Pincer Complexes for the Electrocatalytic Production of Hydrogen. Inorganic Chemistry 2012, 51: 8704-8709. PMID: 22849660, DOI: 10.1021/ic300009a.Peer-Reviewed Original ResearchOrganometallic nickel complexesTridentate pincer ligandsElectrocatalytic proton reductionThird-order rate lawOrder rate lawNickel complexesPincer ligandCatalytic responseProton reductionFaradaic yieldPincer complexesReduction electrocatalysisElectrocatalytic productionCatalytic cycleReduction cycleHydrogen economyComputational studyHydrogen productionRate lawParent compoundCatalystLigandsMechanistic insightsComplexesReactionA tridentate Ni pincer for aqueous electrocatalytic hydrogen production
Luca O, Konezny S, Blakemore J, Colosi D, Saha S, Brudvig G, Batista V, Crabtree R. A tridentate Ni pincer for aqueous electrocatalytic hydrogen production. New Journal Of Chemistry 2012, 36: 1149-1152. DOI: 10.1039/c2nj20912h.Peer-Reviewed Original Research