Accessing Z‐Enynes via Cobalt‐Catalyzed Propargylic Dehydrogenation
Bodnar A, Newhouse T. Accessing Z‐Enynes via Cobalt‐Catalyzed Propargylic Dehydrogenation. Angewandte Chemie International Edition 2024, 63: e202402638. PMID: 38591826, DOI: 10.1002/anie.202402638.Peer-Reviewed Original ResearchKinetic isotope effectsZ-alkenesZ-selectivityCobalt-catalyzedPropargylic positionE-alkenesIsomerization experimentsZ-enyneOrganic synthesisThermodynamic preferenceSubstituted moleculesIsotope effectDehydrogenationRate limiting stepOxide systemsLimiting stepKinetic effectsDeprotonationAlkenesIsomerizationMoleculesSynthesisAccessing Z‐Enynes via Cobalt‐Catalyzed Propargylic Dehydrogenation
Bodnar A, Newhouse T. Accessing Z‐Enynes via Cobalt‐Catalyzed Propargylic Dehydrogenation. Angewandte Chemie 2024, 136 DOI: 10.1002/ange.202402638.Peer-Reviewed Original ResearchKinetic isotope effectsZ-alkenesZ-selectivityCobalt-catalyzedPropargylic positionE-alkenesIsomerization experimentsZ-enyneOrganic synthesisThermodynamic preferenceSubstituted moleculesIsotope effectDehydrogenationRate limiting stepOxide systemsLimiting stepKinetic effectsDeprotonationAlkenesIsomerizationMoleculesSynthesis