2021
THz spectroscopy of emerging materials for light driven processes and energy harvesting
Neu J, Pattengale B, Ostresh S, Capobianco M, Brudvig G. THz spectroscopy of emerging materials for light driven processes and energy harvesting. Proceedings Of SPIE--the International Society For Optical Engineering 2021, 11685: 116850x-116850x-8. DOI: 10.1117/12.2591087.Peer-Reviewed Original ResearchTHz spectroscopyMetal-organic frameworksHigh-frequency propertiesTime-domain THz spectroscopyTHz rangeEnergy harvestingGrain boundariesTerahertz spectroscopyElectrical propertiesCarrier lifetimeNovel materialsDC behaviorSuperior designFrequency propertiesOrganic frameworksConductivity methodMaterialsPhonon modesCharge transferLow frequencyPropertiesSpectroscopy
2013
Synthesis and Properties of NHC-Supported Palladium(I) Dimers with Bridging Allyl, Cyclopentadienyl, and Indenyl Ligands
Dai W, Chalkley M, Brudvig G, Hazari N, Melvin P, Pokhrel R, Takase M. Synthesis and Properties of NHC-Supported Palladium(I) Dimers with Bridging Allyl, Cyclopentadienyl, and Indenyl Ligands. Organometallics 2013, 32: 5114-5127. DOI: 10.1021/om400687m.Peer-Reviewed Original Research
2005
High‐Spin Chloro Mononuclear MnIII Complexes: A Multifrequency High‐Field EPR Study
Mantel C, Chen H, Crabtree R, Brudvig G, Pécaut J, Collomb M, Duboc C. High‐Spin Chloro Mononuclear MnIII Complexes: A Multifrequency High‐Field EPR Study. ChemPhysChem 2005, 6: 541-546. PMID: 15799481, DOI: 10.1002/cphc.200400484.Peer-Reviewed Original ResearchConceptsElectronic propertiesLigand field strengthHigh-Field EPR StudyPorphyrinic systemsTridentate ligandMnIII complexesDistorted octahedronLigands decreasesSolid stateJahn-Teller distortionPrevious complexesStructural characterizationCrystallographic dataEPR studiesMultifrequency EPRManganese ionsComplexesOctahedraTetragonal distortionE termDifferent temperaturesAnionsEPRLigandsProperties
1987
The tetranuclear manganese complex of Photosystem II
Brudvig G. The tetranuclear manganese complex of Photosystem II. Journal Of Bioenergetics And Biomembranes 1987, 19: 91-104. PMID: 3034873, DOI: 10.1007/bf00762719.Peer-Reviewed Original ResearchConceptsManganese complexesElectron paramagnetic resonance (EPR) spectroscopic studiesManganese ionsS2 stateTetranuclear manganese complexPhotosystem IIFour-electron oxidationIntermediate oxidation statesDisplacement of O2Coordination chemistryOxidation stateO bondSpectroscopic studiesS4 stateMagnetic propertiesComplexesIonsLike structureManganeseMn4O4ChemistryStructureBondsOxidationProperties