2021
Organometallic complexes as preferred precursors to form molecular Ir(pyalk) coordination complexes for catalysis of oxygen evolution
Hu G, Crabtree R, Brudvig G. Organometallic complexes as preferred precursors to form molecular Ir(pyalk) coordination complexes for catalysis of oxygen evolution. Inorganica Chimica Acta 2021, 526: 120507. DOI: 10.1016/j.ica.2021.120507.Peer-Reviewed Original ResearchOrganometallic complexesCoordination complexesCatalyst precursorsOrganometallic ligandsOrganometallic precursorsOxygen evolution catalystsUseful catalyst precursorsBlue solutionPyalk ligandCoordination precursorsChelating ligandHomogeneous catalystsIrOx nanoparticlesActive speciesNanoparticle formationNanoparticle generationOxygen evolutionIsomeric mixtureOxidative activationCore unitLigandsCatalystComplexesActivation processPrecursors
2011
Anodic deposition of a robust iridium-based water-oxidation catalyst from organometallic precursors
Blakemore J, Schley N, Olack G, Incarvito C, Brudvig G, Crabtree R. Anodic deposition of a robust iridium-based water-oxidation catalyst from organometallic precursors. Chemical Science 2011, 2: 94-98. DOI: 10.1039/c0sc00418a.Peer-Reviewed Original ResearchWater oxidation catalystsOrganometallic precursorsAnodic depositionRobust water oxidation catalystsLight-driven oxidationInorganic heterogeneous catalystsArtificial photosynthesisWater oxidationCatalyst materialsHeterogeneous catalystsFour-electronAqueous solutionCatalystPhotosystem IIOxidationPrecursorsSustainable sourceElectrodepositionIridiumDepositionMaterialsComplexesReactionOxygenAqua