2018
Some crystal growth strategies for diffraction structure studies of iridium complexes
Sharninghausen L, Sinha S, Shopov D, Brudvig G, Crabtree R. Some crystal growth strategies for diffraction structure studies of iridium complexes. Inorganica Chimica Acta 2018, 480: 183-188. DOI: 10.1016/j.ica.2018.05.017.Peer-Reviewed Original ResearchHydrogen bonding groupsHigher oxidation statesCrystal growth strategiesLarge enough crystalsCluster anionsIr complexesCluster cationsIridium complexesHydrogen bondingOxidation stateStandard crystallization methodsGel methodBonding groupsEnough crystalsCrystallization methodStructure studiesComplexesNeutron diffractionAnionsCationsHydrideBondingDiolDiffractionButane
2005
High‐Spin Chloro Mononuclear MnIII Complexes: A Multifrequency High‐Field EPR Study
Mantel C, Chen H, Crabtree R, Brudvig G, Pécaut J, Collomb M, Duboc C. High‐Spin Chloro Mononuclear MnIII Complexes: A Multifrequency High‐Field EPR Study. ChemPhysChem 2005, 6: 541-546. PMID: 15799481, DOI: 10.1002/cphc.200400484.Peer-Reviewed Original ResearchConceptsElectronic propertiesLigand field strengthHigh-Field EPR StudyPorphyrinic systemsTridentate ligandMnIII complexesDistorted octahedronLigands decreasesSolid stateJahn-Teller distortionPrevious complexesStructural characterizationCrystallographic dataEPR studiesMultifrequency EPRManganese ionsComplexesOctahedraTetragonal distortionE termDifferent temperaturesAnionsEPRLigandsProperties