Exfoliation of a metal–organic framework enabled by post-synthetic cleavage of a dipyridyl dianthracene ligand
Logelin M, Schreiber E, Mercado B, Burke M, Davis C, Bartholomew A. Exfoliation of a metal–organic framework enabled by post-synthetic cleavage of a dipyridyl dianthracene ligand. Chemical Science 2024, 15: 15198-15204. PMID: 39246333, PMCID: PMC11378025, DOI: 10.1039/d4sc03524k.Peer-Reviewed Original ResearchMetal-organic frameworksZinc metal-organic frameworkStacking axisConductive 2D metal–organic frameworksThree-dimensional MOFsTwo-dimensional (2D) metal-organic frameworksCrystals of 2D materialsStimuli-responsive ligandsSynthetic tunabilityImproved crystal growthTwo-dimensional frameworkStacking directionMacroscopic crystalsDimeric ligandsLigandChemo-sensingCrystal growthStructural analysisNanoscale applicationsDianthraceneStackExfoliationAnthraceneDipyridylIncreasing order