Complexes of Iron(II), Cobalt(II), and Nickel(II) with DOTA-Tetraglycinate for pH and Temperature Imaging Using Hyperfine Shifts of an Amide Moiety
Mishra S, Zakaria A, Mihailovic J, Maritim S, Mercado B, Coman D, Hyder F. Complexes of Iron(II), Cobalt(II), and Nickel(II) with DOTA-Tetraglycinate for pH and Temperature Imaging Using Hyperfine Shifts of an Amide Moiety. Inorganic Chemistry 2024, 63: 22559-22571. PMID: 39533962, DOI: 10.1021/acs.inorgchem.4c04023.Peer-Reviewed Original ResearchParamagnetic complexesDivalent transition-metal ionsNitrogen donor atomsLanthanide metal ionsComplexes of iron(IITransition-metal ionsChemical exchange saturation transferDonor atomsAmide moietyCrystallographic dataCoordination numberHyperfine shiftsMetal ionsPH sensitivityMoietyProtonIonsLow cytotoxicityPH imagingSaturation transferMagnetic resonanceCobalt(IINickel(IIIron(IILanthanide