Toward Fully Controllable Monomers Sequence: Binary Organocatalyzed Polymerization from Epoxide/Aziridine/Cyclic Anhydride Monomer Mixture
Gao T, Xia X, Watanabe T, Ke C, Suzuki R, Yamamoto T, Li F, Isono T, Satoh T. Toward Fully Controllable Monomers Sequence: Binary Organocatalyzed Polymerization from Epoxide/Aziridine/Cyclic Anhydride Monomer Mixture. Journal Of The American Chemical Society 2024 PMID: 39086123, DOI: 10.1021/jacs.4c08009.Peer-Reviewed Original ResearchRing-opening alternating copolymerizationMonomer sequenceDensity functional theory calculationsCopolymerization of epoxidesBinary catalyst systemFunctional theory calculationsBlock-like copolymerLewis acidSequence of monomersCatalyst systemCyclic anhydridesArrangement of monomersOrganocatalyzed polymerizationSynthetic methodTheory calculationsCatalytic reactionsPolymer chainsIntrinsic reactivityPoly(ester-amideBlock copolymersPolymer propertiesPolymer scienceAnhydrideCatalyst ratioMonomer mixtureSynthesis of amino-functionalized polyester via ring-opening alternating copolymerization of glycidylamines with cyclic anhydrides
Suzuki R, Gao T, Sumi A, Yamamoto T, Tajima K, Li F, Isono T, Satoh T. Synthesis of amino-functionalized polyester via ring-opening alternating copolymerization of glycidylamines with cyclic anhydrides. Polymer Chemistry 2024 DOI: 10.1039/d4py00715h.Peer-Reviewed Original ResearchRing-opening alternating copolymerizationCyclic anhydridesPhthalic anhydridePolymeric materialsAlkali metal carboxylatesChain extension studiesChain-growth polymerizationFunctional end groupsSide chain structurePhosphazene baseControlled/living natureMonomer scopeMetal carboxylatesEnd groupsBlock copolyestersAnhydrideSynthetic pathwayStructural diversityPolymerizationMonomerMolecular weightAntibacterial materialsPolyesterSynthesisAlcohol initiation