Chemically Recyclable Unnatural (1→6)-Polysaccharides from Cellulose-Derived Levoglucosenone and Dihydrolevoglucosenone
Mizukami Y, Kakehi Y, Li F, Yamamoto T, Tajima K, Isono T, Satoh T. Chemically Recyclable Unnatural (1→6)-Polysaccharides from Cellulose-Derived Levoglucosenone and Dihydrolevoglucosenone. ACS Macro Letters 2024, 13: 252-259. PMID: 38334272, DOI: 10.1021/acsmacrolett.3c00720.Peer-Reviewed Original ResearchClosed-loop chemical recyclingTransparent self-standing filmsCationic ring-opening polymerizationRing-opening polymerizationSelf-standing filmsUnnatural polysaccharidesSubstituent patternChemical spaceAcid catalystMonomer synthesisSynthetic complexesChemical synthesisPolymer materialsLevoglucosenoneThermal stabilityPolymerization kineticsChemical recyclingAmbient conditionsCellulose-derivativesAmorphous solidsDihydrolevoglucosenonePolymerizationMonomerPolymerMaterial properties