Toward Fully Controllable Monomers Sequence: Binary Organocatalyzed Polymerization from Epoxide/Aziridine/Cyclic Anhydride Monomer Mixture
Gao T, Xia X, Watanabe T, Ke C, Suzuki R, Yamamoto T, Li F, Isono T, Satoh T. Toward Fully Controllable Monomers Sequence: Binary Organocatalyzed Polymerization from Epoxide/Aziridine/Cyclic Anhydride Monomer Mixture. Journal Of The American Chemical Society 2024 PMID: 39086123, DOI: 10.1021/jacs.4c08009.Peer-Reviewed Original ResearchRing-opening alternating copolymerizationMonomer sequenceDensity functional theory calculationsCopolymerization of epoxidesBinary catalyst systemFunctional theory calculationsBlock-like copolymerLewis acidSequence of monomersCatalyst systemCyclic anhydridesArrangement of monomersOrganocatalyzed polymerizationSynthetic methodTheory calculationsCatalytic reactionsPolymer chainsIntrinsic reactivityPoly(ester-amideBlock copolymersPolymer propertiesPolymer scienceAnhydrideCatalyst ratioMonomer mixture