Hot Hole Hopping in a Polyoxotitanate Cluster Terminated with Catechol Electron Donors
Bao J, Gundlach L, Yu Z, Benedict J, Snoeberger R, Batista V, Coppens P, Piotrowiak P. Hot Hole Hopping in a Polyoxotitanate Cluster Terminated with Catechol Electron Donors. The Journal Of Physical Chemistry C 2016, 120: 20006-20015. DOI: 10.1021/acs.jpcc.6b06042.Peer-Reviewed Original ResearchPolyoxotitanate clustersQuantum dynamics simulationsIntramolecular vibrational relaxationHole hoppingUltrafast spectroscopyPolaronic excitonsWavepacket propagationInjected electronsPolaronic statesVibrational relaxationCharge transfer bandCharge-separated stateHot holesConduction bandMolecular orbitalsElectronsDepolarization measurementsCatechol ligandInorganic coreCatechol siteCatechol moietyHoppingHolesElectron donorTiO2 coreRutile TiO2 as an Anode Material for Water-Splitting Dye-Sensitized Photoelectrochemical Cells
Swierk J, Regan K, Jiang J, Brudvig G, Schmuttenmaer C. Rutile TiO2 as an Anode Material for Water-Splitting Dye-Sensitized Photoelectrochemical Cells. ACS Energy Letters 2016, 1: 603-606. DOI: 10.1021/acsenergylett.6b00279.Peer-Reviewed Original ResearchWater-splitting dye-sensitized photoelectrochemical cellsPhotoelectrochemical cellsDye-sensitized photoelectrochemical cellsR-TiO2Sensitized Photoelectrochemical CellsWater-Splitting DyeWater oxidation catalystsLight-absorbing dyeWide bandgap metal oxide semiconductorsWater oxidationWS-DSPECsRedox mediatorAnode materialsInjection yieldLight harvesterPhotocurrent generationMetal oxide semiconductorDye stabilityAnatase TiO2Rutile polymorphTiO2Injected electronsRutile TiO2Oxide semiconductorsDye
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