2024
Kinetic Studies of CO2 Insertion into Metal–Element σ‑Bonds
Hazari N. Kinetic Studies of CO2 Insertion into Metal–Element σ‑Bonds. Accounts Of Chemical Research 2024, 57: 2847-2858. PMID: 39268567, DOI: 10.1021/acs.accounts.4c00440.Peer-Reviewed Original ResearchOuter-sphere processS bondsPresence of Lewis acidsKinetic studiesDimroth-Reichardt parameterMetal-catalyzed reactionsImproved catalytic performanceC-C bondsInner-sphere processAncillary ligandsCO2 insertionStronger donorAlkyl ligandsElectron-donatingLewis acidSteric bulkSolvent effectsCatalytic performanceReaction solventMetal alkylsNucleophilic attackLigand effectAlkyl groupsGeneration of fuelsSolvent increases
2023
Efficient O -demethylation of lignin-derived aromatic compounds under moderate conditions
Wang Y, Chen M, Yang Y, Ralph J, Pan X. Efficient O -demethylation of lignin-derived aromatic compounds under moderate conditions. RSC Advances 2023, 13: 5925-5932. PMID: 36816077, PMCID: PMC9936356, DOI: 10.1039/d3ra00245d.Peer-Reviewed Original ResearchElectron-withdrawing substituentsCarbonyl groupAlkyl hydroxyl groupsModerate conditionsElectron-donatingMethoxy groupAlkyl hydroxylationHydroxyl groupsStable intermediateLithium bromideAromatic compoundsAromaticsSubstituentsLignin depolymerizationAromatic chemicalsO-demethylationCarbonylLignin-derived aromaticsAlkylationEfficient methodBromideLignin-derived aromatic compoundsHydroxylCompoundsIntermediate
This site is protected by hCaptcha and its Privacy Policy and Terms of Service apply