2019
Synthesis of Homoallylic Alcohols with Acyclic Quaternary Centers through CoIII‐Catalyzed Three‐Component C−H Bond Addition to Internally Substituted Dienes and Carbonyls
Dongbang S, Shen Z, Ellman J. Synthesis of Homoallylic Alcohols with Acyclic Quaternary Centers through CoIII‐Catalyzed Three‐Component C−H Bond Addition to Internally Substituted Dienes and Carbonyls. Angewandte Chemie 2019, 131: 12720-12724. DOI: 10.1002/ange.201906633.Peer-Reviewed Original ResearchAcyclic Quaternary CentersRelative stereochemistryHomoallylic alcoholsQuaternary centerThree-component strategyBond activationΣ-bondBond additionStereogenic centersCo IIIHigh diastereoselectivityDieneSequential additionThree-componentStereochemistrySubstrate combinationsAlcoholCarbonylAldehydesBondsKetonesDiastereoselectivitySynthesisReactionSynthesis of Homoallylic Alcohols with Acyclic Quaternary Centers through CoIII‐Catalyzed Three‐Component C−H Bond Addition to Internally Substituted Dienes and Carbonyls
Dongbang S, Shen Z, Ellman J. Synthesis of Homoallylic Alcohols with Acyclic Quaternary Centers through CoIII‐Catalyzed Three‐Component C−H Bond Addition to Internally Substituted Dienes and Carbonyls. Angewandte Chemie International Edition 2019, 58: 12590-12594. PMID: 31310435, PMCID: PMC6713593, DOI: 10.1002/anie.201906633.Peer-Reviewed Original ResearchConceptsAcyclic Quaternary CentersRelative stereochemistryHomoallylic alcoholsQuaternary centerH bond activationThree-component strategyBond activationBond additionΣ-bondEfficient COStereogenic centersHigh diastereoselectivitySequential additionDieneThree-componentStereochemistrySubstrate combinationsAlcoholAldehydesCarbonylBondsKetonesDiastereoselectivitySynthesisCO
2018
RhIII‐Catalyzed Synthesis of Isoquinolones and 2‐Pyridones by Annulation of N‐Methoxyamides and Nitroalkenes
Potter TJ, Li Y, Ward MD, Ellman JA. RhIII‐Catalyzed Synthesis of Isoquinolones and 2‐Pyridones by Annulation of N‐Methoxyamides and Nitroalkenes. European Journal Of Organic Chemistry 2018, 2018: 4381-4388. PMID: 30220876, PMCID: PMC6136657, DOI: 10.1002/ejoc.201800745.Peer-Reviewed Original ResearchSingle-crystal X-ray diffractionCrystal X-ray diffractionX-ray diffractionInclusion complexesH bondsHost frameworkN-methoxyamidesRelative stereochemistryNitroalkenesAnnulationAromatic nitroalkenesIsoquinolonesRoom temperatureSynthesisAlkenylStereochemistryMethoxyamidesBondsAromaticsDiffractionCompoundsComplexesAcidMaterialsOil
1987
Bissetone, a unique antimicrobial pyranone from the gorgonian Briareu polyanthes
Cardellina J, Hendrickson R, Manfredi K, Strobel S, Clardy J. Bissetone, a unique antimicrobial pyranone from the gorgonian Briareu polyanthes. Tetrahedron Letters 1987, 28: 727-730. DOI: 10.1016/s0040-4039(01)80973-4.Peer-Reviewed Original Research
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