2023
Engineering Band Gap and Photoconduction in Semiconducting Metal Organic Frameworks: Metal Node Effect
Nyakuchena J, Ostresh S, Neu J, Streater D, Cody C, Hooper R, Zhang X, Reinhart B, Brudvig G, Huang J. Engineering Band Gap and Photoconduction in Semiconducting Metal Organic Frameworks: Metal Node Effect. The Journal Of Physical Chemistry Letters 2023, 14: 5960-5965. PMID: 37345878, DOI: 10.1021/acs.jpclett.3c00499.Peer-Reviewed Original ResearchMetal nodesMetal charge-transfer stateMetal-organic frameworksSquare-planar coordinationCharge transfer stateMixed valence stateBand gapX-ray absorptionTime-resolved opticalOrganic frameworksSmall band gapPhotophysical propertiesPlanar coordinationTransfer statePhotocatalytic propertiesValence stateStructural preferencesMOFOctahedral sphereEngineering band gap
2009
Deposition of an oxomanganese water oxidation catalyst on TiO 2 nanoparticles : computational modeling, assembly and characterization
Li G, Sproviero E, Snoeberger R, Iguchi N, Blakemore J, Crabtree R, Brudvig G, Batista V. Deposition of an oxomanganese water oxidation catalyst on TiO 2 nanoparticles : computational modeling, assembly and characterization. Energy & Environmental Science 2009, 2: 230-238. DOI: 10.1039/b818708h.Peer-Reviewed Original ResearchWater oxidation catalystsOxidation catalystTiO2 nanoparticlesUV-visible spectroscopyTiO 2 nanoparticlesMixed valence stateAmorphous TiO2 nanoparticlesWater ligandsElectrochemical studiesElectrochemical measurementsEPR spectroscopySurface complexesMimic photosynthesisDirect adsorptionSitu synthesisTiO2 surfaceSuccessful attachmentEPR dataNanoparticlesCatalystSolar cellsSpectroscopyComputational modelingAdsorptionEPR