2021
Observation of a potential-dependent switch of water-oxidation mechanism on Co-oxide-based catalysts
Lang C, Li J, Yang K, Wang Y, He D, Thorne J, Croslow S, Dong Q, Zhao Y, Prostko G, Brudvig G, Batista V, Waegele M, Wang D. Observation of a potential-dependent switch of water-oxidation mechanism on Co-oxide-based catalysts. Chem 2021, 7: 2101-2117. DOI: 10.1016/j.chempr.2021.03.015.Peer-Reviewed Original ResearchWater oxidation mechanismWater oxidation reactionWater nucleophilic attack mechanismCo-based catalystsO bond formationNucleophilic attack mechanismKey elementary stepsHeterogeneous catalystsSalt electrolyteElectrode potentialApplied potentialBond formationLow driving forceO couplingElementary stepsMechanistic switchCatalystHigh driving forceDriving forceReactionAttack mechanismWater activityElectrolyteHereinPotential8.22 Oxygen Evolution of Photosystem II
Huang H, Brudvig G. 8.22 Oxygen Evolution of Photosystem II. 2021, 569-588. DOI: 10.1016/b978-0-12-409547-2.14871-1.Peer-Reviewed Original ResearchProtein complex photosystem IIWater oxidation reactionPhotosystem IIWater oxidation mechanismOxygen-evolving complexSolar energy storageNatural photosynthesisKey reactionOxygen evolutionEnergy storageReactionPhotosynthesisCurrent knowledgeDetailed mechanismEssential componentGlobal scaleComplexesMechanism
2020
The Mechanism of Substrate Delivery and Activation in the Solar Water Oxidation Reaction of Photosystem II
Lakshmi K, Kalendra V, Banerjee G, Ghosh I, Yang K, Batista V, Brudvig G. The Mechanism of Substrate Delivery and Activation in the Solar Water Oxidation Reaction of Photosystem II. Biophysical Journal 2020, 118: 610a. DOI: 10.1016/j.bpj.2019.11.3292.Peer-Reviewed Original ResearchSolar water oxidation reactionWater oxidation reactionOxidation reactionPhotosystem IIReactionSubstrate delivery
2002
Proton-Coupled Electron Transfer Involving Tyrosine Z in Photosystem II †
Kühne H, Brudvig G. Proton-Coupled Electron Transfer Involving Tyrosine Z in Photosystem II †. The Journal Of Physical Chemistry B 2002, 106: 8189-8196. DOI: 10.1021/jp0206222.Peer-Reviewed Original ResearchO2-evolving complexYZ oxidationOxidation reactionTyrosine ZProton-coupled electron transfer stepsManganese-depleted photosystem IIPhotosystem IIWater oxidation reactionOxidation of waterOxidation of YZElectron transfer stepProton inventory experimentsProton movementWater oxidationElectron transferRedox mechanismNumber of protonsTransfer stepOxidation processOnset temperatureSecondary donorDeuterated samplesOxidationIsotope effectChloride ions
1988
Resolution of the paradox of ammonia and hydroxylamine as substrate analogs for the water-oxidation reaction catalyzed by photosystem II
Beck W, Brudvig G. Resolution of the paradox of ammonia and hydroxylamine as substrate analogs for the water-oxidation reaction catalyzed by photosystem II. Journal Of The American Chemical Society 1988, 110: 1517-1523. DOI: 10.1021/ja00213a026.Peer-Reviewed Original Research