2024
Photochemical Oxidation of Substrate Water Analogs and Halides by Photosystem II
Shin J, Kanyo J, Debus R, Brudvig G. Photochemical Oxidation of Substrate Water Analogs and Halides by Photosystem II. Advanced Energy Materials 2024, 14 DOI: 10.1002/aenm.202401292.Peer-Reviewed Original ResearchWater oxidation catalysisRedox-active cofactorsOxidation catalysisWater oxidationSubstrate photooxidationProtein-pigment complexesRedox chemistryPhotochemical reductionSubstrate waterNative PSIISmall moleculesO 2 evolutionHalidesO-2ChloridePhotooxidationPhotochemical oxidationPSII complexesBound chlorideKinetic profilesPhotosystem IISubstratePutative water channelsCatalystCatalysis
2022
Highly stable preferential carbon monoxide oxidation by dinuclear heterogeneous catalysts
Zhao Y, Dai S, Yang K, Cao S, Materna K, Lant H, Kao L, Feng X, Guo J, Brudvig G, Flytzani-Stephanopoulos M, Batista V, Pan X, Wang D. Highly stable preferential carbon monoxide oxidation by dinuclear heterogeneous catalysts. Proceedings Of The National Academy Of Sciences Of The United States Of America 2022, 120: e2206850120. PMID: 36577066, PMCID: PMC9910598, DOI: 10.1073/pnas.2206850120.Peer-Reviewed Original Research
2015
Comparison of dppf‐Supported Nickel Precatalysts for the Suzuki–Miyaura Reaction: The Observation and Activity of Nickel(I)
Guard L, Beromi M, Brudvig G, Hazari N, Vinyard D. Comparison of dppf‐Supported Nickel Precatalysts for the Suzuki–Miyaura Reaction: The Observation and Activity of Nickel(I). Angewandte Chemie 2015, 127: 13550-13554. DOI: 10.1002/ange.201505699.Peer-Reviewed Original ResearchSuzuki–Miyaura reactionNi II complexesSimilar catalytic activityDppf ligandNickel precatalystsNi precatalystsOxidation stateCatalytic activityPrecatalystHeterocyclic substratesNi 0Potential chemicalI speciesReactionII complexesRoom temperaturePd systemLigandsComplexesChemicalsNiSignificant amountSubstrate
2006
Molecular Recognition in the Selective Oxygenation of Saturated C-H Bonds by a Dimanganese Catalyst
Das S, Incarvito CD, Crabtree RH, Brudvig GW. Molecular Recognition in the Selective Oxygenation of Saturated C-H Bonds by a Dimanganese Catalyst. Science 2006, 312: 1941-1943. PMID: 16809537, DOI: 10.1126/science.1127899.Peer-Reviewed Original ResearchConceptsHydrogen bondingMolecular recognitionH bondsCarboxylic acid groupsMolecular recognition elementsSynthetic catalystsSaturated CKemp's triacidSelective oxygenationCOOH groupRegioselective functionalizationH activationHigh selectivityAcid groupsRecognition groupReactive centerRecognition elementCatalystTriacidOrient substratesSelectivityBondingBondsControl experimentsSubstrate