2023
Multielectrode electrochemical cell for in situ structural characterization of amorphous thin‐film catalysts using high‐energy X‐ray scattering
Kwon G, Kisslinger K, Hwang S, Wright G, Layne B, Zhong H, Pattammattel A, Lynch J, Kim J, Hu G, Brudvig G, Lee W, Nam C. Multielectrode electrochemical cell for in situ structural characterization of amorphous thin‐film catalysts using high‐energy X‐ray scattering. Journal Of Applied Crystallography 2023, 56: 1392-1402. DOI: 10.1107/s1600576723006933.Peer-Reviewed Original ResearchThin film catalystElectrochemical cellGlassy carbonHigh-energy X-ray scatteringStructural characterizationX-ray scatteringWater oxidation catalystsPorous electrode architectureThree-electrode configurationHigh-energy x-ray scattering techniquesSitu structural characterizationPDF analysisIridium oxide filmsMetal oxide layerPair distribution function techniqueElectrode architectureOxidation catalystX-ray Scattering MeasurementsX-ray scattering techniquesReaction conditionsCatalystElectrochemical potentialAtomic pair distribution function (PDF) techniqueElectrodeDeposition technique
2021
Forging O–O Bonds
Cody C, Brudvig G. Forging O–O Bonds. Joule 2021, 5: 1923-1925. DOI: 10.1016/j.joule.2021.07.013.Peer-Reviewed Original Research
2005
High‐Spin Chloro Mononuclear MnIII Complexes: A Multifrequency High‐Field EPR Study
Mantel C, Chen H, Crabtree R, Brudvig G, Pécaut J, Collomb M, Duboc C. High‐Spin Chloro Mononuclear MnIII Complexes: A Multifrequency High‐Field EPR Study. ChemPhysChem 2005, 6: 541-546. PMID: 15799481, DOI: 10.1002/cphc.200400484.Peer-Reviewed Original ResearchConceptsElectronic propertiesLigand field strengthHigh-Field EPR StudyPorphyrinic systemsTridentate ligandMnIII complexesDistorted octahedronLigands decreasesSolid stateJahn-Teller distortionPrevious complexesStructural characterizationCrystallographic dataEPR studiesMultifrequency EPRManganese ionsComplexesOctahedraTetragonal distortionE termDifferent temperaturesAnionsEPRLigandsProperties
2000
Characterization of the O2-Evolving Reaction Catalyzed by [(terpy)(H2O)MnIII(O)2MnIV(OH2)(terpy)](NO3)3 (terpy = 2,2‘:6,2‘ ‘-Terpyridine)
Limburg J, Vrettos J, Chen H, de Paula J, Crabtree R, Brudvig G. Characterization of the O2-Evolving Reaction Catalyzed by [(terpy)(H2O)MnIII(O)2MnIV(OH2)(terpy)](NO3)3 (terpy = 2,2‘:6,2‘ ‘-Terpyridine). Journal Of The American Chemical Society 2000, 123: 423-430. PMID: 11456544, DOI: 10.1021/ja001090a.Peer-Reviewed Original Research