2022
Highly stable preferential carbon monoxide oxidation by dinuclear heterogeneous catalysts
Zhao Y, Dai S, Yang K, Cao S, Materna K, Lant H, Kao L, Feng X, Guo J, Brudvig G, Flytzani-Stephanopoulos M, Batista V, Pan X, Wang D. Highly stable preferential carbon monoxide oxidation by dinuclear heterogeneous catalysts. Proceedings Of The National Academy Of Sciences Of The United States Of America 2022, 120: e2206850120. PMID: 36577066, PMCID: PMC9910598, DOI: 10.1073/pnas.2206850120.Peer-Reviewed Original Research
2020
Surface-Attached Molecular Catalysts on Visible-Light-Absorbing Semiconductors: Opportunities and Challenges for a Stable Hybrid Water-Splitting Photoanode
Liu H, Cody C, Jayworth J, Crabtree R, Brudvig G. Surface-Attached Molecular Catalysts on Visible-Light-Absorbing Semiconductors: Opportunities and Challenges for a Stable Hybrid Water-Splitting Photoanode. ACS Energy Letters 2020, 5: 3195-3202. DOI: 10.1021/acsenergylett.0c01719.Peer-Reviewed Original ResearchMolecular water oxidation catalystsWater splitting photoanodesSolar fuel generationWater oxidation catalystsHybrid photoanodeLong-term stabilityMolecular catalystsFuel generationCharacterization techniquesPhotoanodeStudy of degradationGreat promiseCell consistsCatalystPractical applicationsSemiconductorsDesign strategyStabilityCrucial subjectFuture directionsApplicationsPromiseDegradation
2017
Synthesis and Characterization of Iridium(V) Coordination Complexes With an N,O‐Donor Organic Ligand
Sharninghausen L, Sinha S, Shopov D, Mercado B, Balcells D, Brudvig G, Crabtree R. Synthesis and Characterization of Iridium(V) Coordination Complexes With an N,O‐Donor Organic Ligand. Angewandte Chemie 2017, 129: 13227-13231. DOI: 10.1002/ange.201707593.Peer-Reviewed Original ResearchCoordination complexesO-donor organic ligandsMononuclear coordination complexesO-donor environmentMetal-centered oxidationX-ray crystallographyOrganic ligandsDonor strengthAlkoxide groupsDFT calculationsD orbitalsUnprecedented stabilityComplexesLigandsOxidationIR-VIsomersXPSCrystallographyV complexSynthesisCharacterizationStabilityCalculationsDegradation
2011
A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst
Moore G, Blakemore J, Milot R, Hull J, Song H, Cai L, Schmuttenmaer C, Crabtree R, Brudvig G. A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst. Energy & Environmental Science 2011, 4: 2389-2392. DOI: 10.1039/c1ee01037a.Peer-Reviewed Original Research