2021
Organometallic complexes as preferred precursors to form molecular Ir(pyalk) coordination complexes for catalysis of oxygen evolution
Hu G, Crabtree R, Brudvig G. Organometallic complexes as preferred precursors to form molecular Ir(pyalk) coordination complexes for catalysis of oxygen evolution. Inorganica Chimica Acta 2021, 526: 120507. DOI: 10.1016/j.ica.2021.120507.Peer-Reviewed Original ResearchOrganometallic complexesCoordination complexesCatalyst precursorsOrganometallic ligandsOrganometallic precursorsOxygen evolution catalystsUseful catalyst precursorsBlue solutionPyalk ligandCoordination precursorsChelating ligandHomogeneous catalystsIrOx nanoparticlesActive speciesNanoparticle formationNanoparticle generationOxygen evolutionIsomeric mixtureOxidative activationCore unitLigandsCatalystComplexesActivation processPrecursors
2015
Hematite‐Based Solar Water Splitting in Acidic Solutions: Functionalization by Mono‐ and Multilayers of Iridium Oxygen‐Evolution Catalysts
Li W, Sheehan S, He D, He Y, Yao X, Grimm R, Brudvig G, Wang D. Hematite‐Based Solar Water Splitting in Acidic Solutions: Functionalization by Mono‐ and Multilayers of Iridium Oxygen‐Evolution Catalysts. Angewandte Chemie 2015, 127: 11590-11594. DOI: 10.1002/ange.201504427.Peer-Reviewed Original ResearchWater oxidation catalystsSolar water splittingWater splittingAcidic solutionMolecular water oxidation catalystsStable water oxidation catalystsNear-unity Faradaic efficiencyOxygen evolution catalystsStable solar water splittingFaradaic efficiencyPhotoelectrochemical cellsImportant technological implicationsCatalystLow pHMonolayers