2024
Complexes of Iron(II), Cobalt(II), and Nickel(II) with DOTA-Tetraglycinate for pH and Temperature Imaging Using Hyperfine Shifts of an Amide Moiety
Mishra S, Zakaria A, Mihailovic J, Maritim S, Mercado B, Coman D, Hyder F. Complexes of Iron(II), Cobalt(II), and Nickel(II) with DOTA-Tetraglycinate for pH and Temperature Imaging Using Hyperfine Shifts of an Amide Moiety. Inorganic Chemistry 2024, 63: 22559-22571. PMID: 39533962, DOI: 10.1021/acs.inorgchem.4c04023.Peer-Reviewed Original ResearchParamagnetic complexesDivalent transition-metal ionsNitrogen donor atomsLanthanide metal ionsComplexes of iron(IITransition-metal ionsChemical exchange saturation transferDonor atomsAmide moietyCrystallographic dataCoordination numberHyperfine shiftsMetal ionsPH sensitivityMoietyProtonIonsLow cytotoxicityPH imagingSaturation transferMagnetic resonanceCobalt(IINickel(IIIron(IILanthanide
2012
Iridium Complexes of Bulky CCC-Pincer N‑Heterocyclic Carbene Ligands: Steric Control of Coordination Number and Catalytic Alkene Isomerization
Chianese A, Shaner S, Tendler J, Pudalov D, Shopov D, Kim D, Rogers S, Mo A. Iridium Complexes of Bulky CCC-Pincer N‑Heterocyclic Carbene Ligands: Steric Control of Coordination Number and Catalytic Alkene Isomerization. Organometallics 2012, 31: 7359-7367. DOI: 10.1021/om300468d.Peer-Reviewed Original ResearchIridium complexesN-substituentsIsomerization of terminal alkenesFive-coordinate iridium(IIIIridium(III) complexesPincer ligandTransfer dehydrogenationAlkene isomerizationSteric controlTerminal alkenesActive catalystCoordination numberT-butylIridiumLigandN-octaneCatalystIsomerizationComplexIridium(IIIAlkenesPincerCatalyticallyReactionDerivativesChemInform Abstract: Observation of the Highest Coordination Number in Planar Species: Decacoordinated Ta©B10‐ and Nb©B10‐ Anions.
Galeev T, Romanescu C, Li W, Wang L, Boldyrev A. ChemInform Abstract: Observation of the Highest Coordination Number in Planar Species: Decacoordinated Ta©B10‐ and Nb©B10‐ Anions. ChemInform 2012, 43: no-no. DOI: 10.1002/chin.201219001.Peer-Reviewed Original ResearchObservation of the Highest Coordination Number in Planar Species: Decacoordinated Ta©B10− and Nb©B10− Anions
Galeev T, Romanescu C, Li W, Wang L, Boldyrev A. Observation of the Highest Coordination Number in Planar Species: Decacoordinated Ta©B10− and Nb©B10− Anions. Angewandte Chemie International Edition 2012, 51: 2101-2105. PMID: 22298320, DOI: 10.1002/anie.201107880.Peer-Reviewed Original ResearchLaser-vaporization supersonic molecular beamsCoordination numberHigh coordination numberAb initio calculationsSupersonic molecular beamPhotoelectron spectroscopyPlanar speciesMolecular wheelsCentral atomΠ-electronsPlanar environmentInitio calculationsΣ electronsAnionsMolecular beamElectronsSpectroscopyAtomsNbTaCalculations
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