Mechanistic Studies of Alkene Isomerization Catalyzed by CCC-Pincer Complexes of Iridium
Knapp S, Shaner S, Kim D, Shopov D, Tendler J, Pudalov D, Chianese A. Mechanistic Studies of Alkene Isomerization Catalyzed by CCC-Pincer Complexes of Iridium. Organometallics 2014, 33: 473-484. DOI: 10.1021/om400786r.Peer-Reviewed Original ResearchAlkene isomerizationC-H reductive eliminationN-heterocyclic carbene ligandsCatalyst resting stateComplexes of iridiumLigand steric effectsMechanistic studiesTransfer of hydrogenCarbene ligandsInsertion/elimination mechanismCompetent catalystsHydride intermediateReductive eliminationIridium complexesLigand substitutionHydride speciesMetal alkylsSteric effectsIntermolecular transferIsomerization reactionSide groupsNMR experimentsAlkenesInternal isomersIsomerization
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