2006
Rhodium-Catalyzed Direct C−H Addition of 3,4-Dihydroquinazolines to Alkenes and Their Use in the Total Synthesis of Vasicoline
Wiedemann SH, Ellman JA, Bergman RG. Rhodium-Catalyzed Direct C−H Addition of 3,4-Dihydroquinazolines to Alkenes and Their Use in the Total Synthesis of Vasicoline. The Journal Of Organic Chemistry 2006, 71: 1969-1976. PMID: 16496982, DOI: 10.1021/jo052345b.Peer-Reviewed Original Research
2005
Preagostic Rh−H Interactions and C−H Bond Functionalization: A Combined Experimental and Theoretical Investigation of Rhodium(I) Phosphinite Complexes
Lewis J, Wu J, Bergman R, Ellman J. Preagostic Rh−H Interactions and C−H Bond Functionalization: A Combined Experimental and Theoretical Investigation of Rhodium(I) Phosphinite Complexes. Organometallics 2005, 24: 5737-5746. DOI: 10.1021/om050700i.Peer-Reviewed Original ResearchPreagostic interactionsChemical shielding calculationsSolid-state dataGeneral structural formulaPhosphinite complexesBond functionalizationModel complexesDFT calculationsCatalytic cycleSpectroscopic techniquesOrtho alkylationUnactivated alkenesCyclometalation stepStructural formulaRare exampleComplexesTheoretical investigationShielding calculationsFunctionalizationPhosphinitesAlkenesAlkylationCrystallographicCalculationsPhenol
2004
Intermolecular Coupling of Alkenes to Heterocycles via C−H Bond Activation
Tan KL, Park S, Ellman JA, Bergman RG. Intermolecular Coupling of Alkenes to Heterocycles via C−H Bond Activation. The Journal Of Organic Chemistry 2004, 69: 7329-7335. PMID: 15471487, DOI: 10.1021/jo048666p.Peer-Reviewed Original Research
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