Preagostic Rh−H Interactions and C−H Bond Functionalization: A Combined Experimental and Theoretical Investigation of Rhodium(I) Phosphinite Complexes
Lewis J, Wu J, Bergman R, Ellman J. Preagostic Rh−H Interactions and C−H Bond Functionalization: A Combined Experimental and Theoretical Investigation of Rhodium(I) Phosphinite Complexes. Organometallics 2005, 24: 5737-5746. DOI: 10.1021/om050700i.Peer-Reviewed Original ResearchPreagostic interactionsChemical shielding calculationsSolid-state dataGeneral structural formulaPhosphinite complexesBond functionalizationModel complexesDFT calculationsCatalytic cycleSpectroscopic techniquesOrtho alkylationUnactivated alkenesCyclometalation stepStructural formulaRare exampleComplexesTheoretical investigationShielding calculationsFunctionalizationPhosphinitesAlkenesAlkylationCrystallographicCalculationsPhenol
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