2019
Synthesis and Reactivity of Paramagnetic Nickel Polypyridyl Complexes Relevant to C(sp2)–C(sp3)Coupling Reactions
Beromi M, Brudvig G, Hazari N, Lant H, Mercado B. Synthesis and Reactivity of Paramagnetic Nickel Polypyridyl Complexes Relevant to C(sp2)–C(sp3)Coupling Reactions. Angewandte Chemie 2019, 131: 6155-6159. DOI: 10.1002/ange.201901866.Peer-Reviewed Original Research
2017
Synthesis of pyridine-alkoxide ligands for formation of polynuclear complexes
Shopov D, Sharninghausen L, Sinha S, Borowski J, Mercado B, Brudvig G, Crabtree R. Synthesis of pyridine-alkoxide ligands for formation of polynuclear complexes. New Journal Of Chemistry 2017, 41: 6709-6719. DOI: 10.1039/c7nj01845b.Peer-Reviewed Original ResearchO-donor ligandsPolynuclear complexesFirst-row transition metalsPyridine-alkoxide ligandsInexpensive starting materialsOne-step synthesisX-ray crystallographyPolynuclear clustersTransition metalsStarting materialScalable procedureGeneral formulaLigandsEffective bindingLarge-scale productionLigand 2Chelation powerComplexesSynthesisDenticityCluster formationDeprotonationFormationCrystallographyChromatography