2006
Determination of μ-Oxo Exchange Rates in Di-μ-Oxo Dimanganese Complexes by Electrospray Ionization Mass Spectrometry
Tagore R, Chen, Crabtree RH, Brudvig GW. Determination of μ-Oxo Exchange Rates in Di-μ-Oxo Dimanganese Complexes by Electrospray Ionization Mass Spectrometry. Journal Of The American Chemical Society 2006, 128: 9457-9465. PMID: 16848483, DOI: 10.1021/ja061348i.Peer-Reviewed Original Research
2005
High‐Spin Chloro Mononuclear MnIII Complexes: A Multifrequency High‐Field EPR Study
Mantel C, Chen H, Crabtree R, Brudvig G, Pécaut J, Collomb M, Duboc C. High‐Spin Chloro Mononuclear MnIII Complexes: A Multifrequency High‐Field EPR Study. ChemPhysChem 2005, 6: 541-546. PMID: 15799481, DOI: 10.1002/cphc.200400484.Peer-Reviewed Original ResearchConceptsElectronic propertiesLigand field strengthHigh-Field EPR StudyPorphyrinic systemsTridentate ligandMnIII complexesDistorted octahedronLigands decreasesSolid stateJahn-Teller distortionPrevious complexesStructural characterizationCrystallographic dataEPR studiesMultifrequency EPRManganese ionsComplexesOctahedraTetragonal distortionE termDifferent temperaturesAnionsEPRLigandsProperties
2003
Raman spectra and normal coordinate analyses of low-frequency vibrations of oxo-bridged manganese complexes
Cua A, Vrettos J, de Paula J, Brudvig G, Bocian D. Raman spectra and normal coordinate analyses of low-frequency vibrations of oxo-bridged manganese complexes. JBIC Journal Of Biological Inorganic Chemistry 2003, 8: 439-451. PMID: 12761665, DOI: 10.1007/s00775-002-0433-4.Peer-Reviewed Original ResearchMeSH KeywordsCrystallizationLigandsManganese CompoundsOrganometallic CompoundsOxygenSpectrum Analysis, RamanVibration
2001
High-Frequency EPR Study of a New Mononuclear Manganese(III) Complex: [(terpy)Mn(N3)3] (terpy = 2,2‘:6‘,2‘ ‘-Terpyridine)
Limburg J, Vrettos J, Crabtree R, Brudvig G, de Paula J, Hassan A, Barra A, Duboc-Toia C, Collomb M. High-Frequency EPR Study of a New Mononuclear Manganese(III) Complex: [(terpy)Mn(N3)3] (terpy = 2,2‘:6‘,2‘ ‘-Terpyridine). Inorganic Chemistry 2001, 40: 1698-1703. PMID: 11261982, DOI: 10.1021/ic001118j.Peer-Reviewed Original ResearchMeSH KeywordsCrystallography, X-RayElectron Spin Resonance SpectroscopyManganese CompoundsModels, MolecularMolecular StructureOrganometallic CompoundsPyridines
1999
A Functional Model for O-O Bond Formation by the O2-Evolving Complex in Photosystem II
Limburg J, Vrettos J, Liable-Sands L, Rheingold A, Crabtree R, Brudvig G. A Functional Model for O-O Bond Formation by the O2-Evolving Complex in Photosystem II. Science 1999, 283: 1524-1527. PMID: 10066173, DOI: 10.1126/science.283.5407.1524.Peer-Reviewed Original ResearchConceptsMolecular oxygenPhotosystem IIO bond formationPhotosynthetic water oxidationWater oxidationManganese dimerBond formationOxygen atomsActive siteIsotope labelingManganese ionsOxygenPhotosynthesisWaterSodium hypochloriteOxidationIonsFormationAtomsDimersComplexesO2Functional modelConversionHypochlorite