Engineering Band Gap and Photoconduction in Semiconducting Metal Organic Frameworks: Metal Node Effect
Nyakuchena J, Ostresh S, Neu J, Streater D, Cody C, Hooper R, Zhang X, Reinhart B, Brudvig G, Huang J. Engineering Band Gap and Photoconduction in Semiconducting Metal Organic Frameworks: Metal Node Effect. The Journal Of Physical Chemistry Letters 2023, 14: 5960-5965. PMID: 37345878, DOI: 10.1021/acs.jpclett.3c00499.Peer-Reviewed Original ResearchMetal nodesMetal charge-transfer stateMetal-organic frameworksSquare-planar coordinationCharge transfer stateMixed valence stateBand gapX-ray absorptionTime-resolved opticalOrganic frameworksSmall band gapPhotophysical propertiesPlanar coordinationTransfer statePhotocatalytic propertiesValence stateStructural preferencesMOFOctahedral sphereEngineering band gap