2024
Selecting between Ammonia and Water Oxidation: Electrochemical Oxidation of Ammonia in Water Using an Organometallic–Inorganic Hybrid Anode
Liu H, Jayworth J, Crabtree R, Brudvig G. Selecting between Ammonia and Water Oxidation: Electrochemical Oxidation of Ammonia in Water Using an Organometallic–Inorganic Hybrid Anode. ACS Catalysis 2024, 14: 2842-2846. DOI: 10.1021/acscatal.3c05899.Peer-Reviewed Original ResearchHybrid anodeWater oxidationBlue layerElectrochemical oxidation of ammoniaOxidation of ammoniaElectrochemical oxidationSurface poisoningAqueous solventAmmonia oxidationOptimal operating conditionsAqueous solutionAmbient conditionsE appOperating conditionsAnodeFormation of nitriteOxidationOptimum selectionAmmoniaSolventNitrateNanoclustersDinitrogenElectrodeEcofriendly products
2016
Solvent Dependence of Lateral Charge Transfer in a Porphyrin Monolayer
Brennan B, Regan K, Durrell A, Schmuttenmaer C, Brudvig G. Solvent Dependence of Lateral Charge Transfer in a Porphyrin Monolayer. ACS Energy Letters 2016, 2: 168-173. DOI: 10.1021/acsenergylett.6b00583.Peer-Reviewed Original ResearchPropylene carbonateRedox-active monolayerCharge transfer kineticsAqueous solvent mixturesCharge transfer mechanismLateral charge transferLateral charge transportPorphyrin monolayersPorphyrin systemsCharge transferSolvent dependenceInfluence of waterSolar energy harvestingSolvent mixturesCharge transportSolventHole hoppingPacking dynamicsMonolayersOrders of magnitudeCarbonateNsSolvationWater