Thermal stability of [Mn(III)(O)2Mn(IV)(H2O)2(Terpy)2](NO3)3 (Terpy=2,2′:6′,2″-terpyridine) in aqueous solution
Zhang F, Cady C, Brudvig G, Hou H. Thermal stability of [Mn(III)(O)2Mn(IV)(H2O)2(Terpy)2](NO3)3 (Terpy=2,2′:6′,2″-terpyridine) in aqueous solution. Inorganica Chimica Acta 2011, 366: 128-133. DOI: 10.1016/j.ica.2010.10.021.Peer-Reviewed Original ResearchOxo dimerMn4Ca clusterAqueous solutionThermal stabilitySolar fuel productionOxygen evolution activityFirst fast stepMn valence changeAtomic absorption spectroscopyCatalytic materialsElemental analysisPS IIManganese dioxideAbsorption spectroscopyConversion of waterNovel MnDimer compoundsMn valenceSlow stepFast stepSolid MnThermal decompositionValence changeUnique materialFuel production