2014
Co( ii ), a catalyst for selective conversion of phenyl rings to carboxylic acid groups
Sinha S, Campos J, Brudvig G, Crabtree R. Co( ii ), a catalyst for selective conversion of phenyl rings to carboxylic acid groups. RSC Advances 2014, 4: 49395-49399. DOI: 10.1039/c4ra10510a.Peer-Reviewed Original Research
2006
Molecular Recognition in the Selective Oxygenation of Saturated C-H Bonds by a Dimanganese Catalyst
Das S, Incarvito CD, Crabtree RH, Brudvig GW. Molecular Recognition in the Selective Oxygenation of Saturated C-H Bonds by a Dimanganese Catalyst. Science 2006, 312: 1941-1943. PMID: 16809537, DOI: 10.1126/science.1127899.Peer-Reviewed Original ResearchConceptsHydrogen bondingMolecular recognitionH bondsCarboxylic acid groupsMolecular recognition elementsSynthetic catalystsSaturated CKemp's triacidSelective oxygenationCOOH groupRegioselective functionalizationH activationHigh selectivityAcid groupsRecognition groupReactive centerRecognition elementCatalystTriacidOrient substratesSelectivityBondingBondsControl experimentsSubstrate