Cp* Iridium Precatalysts for Selective C–H Oxidation with Sodium Periodate As the Terminal Oxidant
Zhou M, Hintermair U, Hashiguchi B, Parent A, Hashmi S, Elimelech M, Periana R, Brudvig G, Crabtree R. Cp* Iridium Precatalysts for Selective C–H Oxidation with Sodium Periodate As the Terminal Oxidant. Organometallics 2013, 32: 957-965. DOI: 10.1021/om301252w.Peer-Reviewed Original ResearchH oxidationTerminal oxidantTime-resolved dynamic light scatteringSodium periodateEfficient terminal oxidantH bond cleavageMetal oxide nanoparticlesDynamic light scatteringFunctional group toleranceKinetic isotope effectsMethylene oxidationRetention of configurationCyclohexane oxidationWater oxidationIridium precatalystBond cleavageSulfonate groupsHomogeneous pathwayH bondsGroup toleranceNatural productsOxide nanoparticlesLight scatteringOxidationUseful yields