2023
Multielectrode electrochemical cell for in situ structural characterization of amorphous thin‐film catalysts using high‐energy X‐ray scattering
Kwon G, Kisslinger K, Hwang S, Wright G, Layne B, Zhong H, Pattammattel A, Lynch J, Kim J, Hu G, Brudvig G, Lee W, Nam C. Multielectrode electrochemical cell for in situ structural characterization of amorphous thin‐film catalysts using high‐energy X‐ray scattering. Journal Of Applied Crystallography 2023, 56: 1392-1402. DOI: 10.1107/s1600576723006933.Peer-Reviewed Original ResearchThin film catalystElectrochemical cellGlassy carbonHigh-energy X-ray scatteringStructural characterizationX-ray scatteringWater oxidation catalystsPorous electrode architectureThree-electrode configurationHigh-energy x-ray scattering techniquesSitu structural characterizationPDF analysisIridium oxide filmsMetal oxide layerPair distribution function techniqueElectrode architectureOxidation catalystX-ray Scattering MeasurementsX-ray scattering techniquesReaction conditionsCatalystElectrochemical potentialAtomic pair distribution function (PDF) techniqueElectrodeDeposition technique
2019
Modification of a pyridine-alkoxide ligand during the synthesis of coordination compounds
Shopov D, Sharninghausen L, Sinha S, Mercado B, Brudvig G, Crabtree R. Modification of a pyridine-alkoxide ligand during the synthesis of coordination compounds. Inorganica Chimica Acta 2019, 484: 75-78. DOI: 10.1016/j.ica.2018.09.020.Peer-Reviewed Original ResearchPyridine-alkoxide ligandsWater oxidation catalysisHigher oxidation statesCoordination compoundsPincer ligandGeminal methyl groupsCatalytic conditionsOxidation stateOxidation catalystReaction conditionsMinor byproductsAliphatic alkenesMinor productsOxidative conditionsMethyl groupN-oxideLigandsBlue solutionCH groupPincerStructural analoguesSynthesisComplexesCatalystCentral unit