2021
Photoinduced Charge Transport in Conductive Metal Organic Frameworks
Ostresh S, Nyakuchena J, Pattenale B, Neu J, Streater D, Fiankor C, Hu W, Kinigstein E, Zhang J, Zhang X, Schmuttenmaer C, Huang J, Brudvig G. Photoinduced Charge Transport in Conductive Metal Organic Frameworks. 2021, 00: 1-2. DOI: 10.1109/irmmw-thz50926.2021.9567551.Peer-Reviewed Original ResearchConductive metal-organic frameworksMetal-organic frameworksPhotocatalytic applicationsCharge transport mechanismOrganic frameworksPorous crystalline materialsCharge transportTerahertzCrystalline materialsTransport mechanismRational designPromising classConductivityApplicationsAbsorption spectroscopyTransient absorption spectroscopyMaterials
2018
Water-Nucleophilic Attack Mechanism for the CuII(pyalk)2 Water-Oxidation Catalyst
Rudshteyn B, Fisher K, Lant H, Yang K, Mercado B, Brudvig G, Crabtree R, Batista V. Water-Nucleophilic Attack Mechanism for the CuII(pyalk)2 Water-Oxidation Catalyst. ACS Catalysis 2018, 8: 7952-7960. DOI: 10.1021/acscatal.8b02466.Peer-Reviewed Original ResearchKinetic isotope effectsWater nucleophilic attack mechanismWater oxidation catalystsWater nucleophilic attackD Kinetic Isotope EffectO bond formationUV-visible spectraDensity functional theoryElectrochemical stepWater oxidationElectrochemical analysisTurnover frequencyDerivative complexesBond formationRadical speciesRational designCis formFunctional theoryIsotope effectRate-limiting stepCatalystComplexesAttack mechanismMechanistic findingsDeprotonation