2016
Solvent Dependence of Lateral Charge Transfer in a Porphyrin Monolayer
Brennan B, Regan K, Durrell A, Schmuttenmaer C, Brudvig G. Solvent Dependence of Lateral Charge Transfer in a Porphyrin Monolayer. ACS Energy Letters 2016, 2: 168-173. DOI: 10.1021/acsenergylett.6b00583.Peer-Reviewed Original ResearchPropylene carbonateRedox-active monolayerCharge transfer kineticsAqueous solvent mixturesCharge transfer mechanismLateral charge transferLateral charge transportPorphyrin monolayersPorphyrin systemsCharge transferSolvent dependenceInfluence of waterSolar energy harvestingSolvent mixturesCharge transportSolventHole hoppingPacking dynamicsMonolayersOrders of magnitudeCarbonateNsSolvationWater
2015
Hematite‐Based Solar Water Splitting in Acidic Solutions: Functionalization by Mono‐ and Multilayers of Iridium Oxygen‐Evolution Catalysts
Li W, Sheehan S, He D, He Y, Yao X, Grimm R, Brudvig G, Wang D. Hematite‐Based Solar Water Splitting in Acidic Solutions: Functionalization by Mono‐ and Multilayers of Iridium Oxygen‐Evolution Catalysts. Angewandte Chemie 2015, 127: 11590-11594. DOI: 10.1002/ange.201504427.Peer-Reviewed Original ResearchWater oxidation catalystsSolar water splittingWater splittingAcidic solutionMolecular water oxidation catalystsStable water oxidation catalystsNear-unity Faradaic efficiencyOxygen evolution catalystsStable solar water splittingFaradaic efficiencyPhotoelectrochemical cellsImportant technological implicationsCatalystLow pHMonolayers