Modification of a pyridine-alkoxide ligand during the synthesis of coordination compounds
Shopov D, Sharninghausen L, Sinha S, Mercado B, Brudvig G, Crabtree R. Modification of a pyridine-alkoxide ligand during the synthesis of coordination compounds. Inorganica Chimica Acta 2019, 484: 75-78. DOI: 10.1016/j.ica.2018.09.020.Peer-Reviewed Original ResearchPyridine-alkoxide ligandsWater oxidation catalysisHigher oxidation statesCoordination compoundsPincer ligandGeminal methyl groupsCatalytic conditionsOxidation stateOxidation catalystReaction conditionsMinor byproductsAliphatic alkenesMinor productsOxidative conditionsMethyl groupN-oxideLigandsBlue solutionCH groupPincerStructural analoguesSynthesisComplexesCatalystCentral unit