Active Sites of Cobalt Phthalocyanine in Electrocatalytic CO2 Reduction to Methanol
Rooney C, Lyons M, Wu Y, Hu G, Wang M, Choi C, Gao Y, Chang C, Brudvig G, Feng Z, Wang H. Active Sites of Cobalt Phthalocyanine in Electrocatalytic CO2 Reduction to Methanol. Angewandte Chemie International Edition 2023, 63: e202310623. PMID: 37820079, DOI: 10.1002/anie.202310623.Peer-Reviewed Original ResearchActive siteCobalt phthalocyanineSitu X-ray absorption spectroscopyX-ray absorption spectroscopy characterizationX-ray absorption spectroscopyElectrocatalytic CO2 reductionStructure-reactivity correlationsAbsorption spectroscopy characterizationElectrocatalytic measurementsMetal coordinationElectrocatalytic performanceCoordination environmentMolecular dispersionRelated porphyrinsCNT surfaceElectron transferAbsorption spectroscopyConductive carbonElectronic interactionsKey intermediateCO2 reductionPc macrocycleReaction mechanismSpectroscopy characterizationMethanol pathway