2000
Kinetic analysis of the O2-forming reaction between [Mn(III)(dpa)2]− (dpa=dipicolinate) and potassium peroxomonosulfate
Limburg J, Crabtree* R, Brudvig* G. Kinetic analysis of the O2-forming reaction between [Mn(III)(dpa)2]− (dpa=dipicolinate) and potassium peroxomonosulfate. Inorganica Chimica Acta 2000, 297: 301-306. DOI: 10.1016/s0020-1693(99)00362-x.Peer-Reviewed Original ResearchO2-evolving complexPotassium peroxomonosulfateO2 evolutionComplexes of formulaO2-evolving reactionsFour-electron oxidationPhotosynthetic water oxidationPhotosystem IITerpy complexesWater oxidationManganese complexesKinetic analysisSide reactionsBond formationMolecular oxygenOxygen atomsReactionComplexesPeroxomonosulfateKey stepOxidationKobsManganeseTerpyridineTerpy
1994
A modified MM2 force field for high-valent di-μ-oxo manganese dimers
Manchanda R, Zimmer M, Brudvig G, Crabtree R. A modified MM2 force field for high-valent di-μ-oxo manganese dimers. Journal Of Molecular Structure 1994, 323: 257-266. DOI: 10.1016/0022-2860(94)08304-5.Peer-Reviewed Original Research
1989
Bioinorganic Chemistry of Manganese Related to Photosynthetic Oxygen Evolution
Brudvig G, Crabtree R. Bioinorganic Chemistry of Manganese Related to Photosynthetic Oxygen Evolution. Progress In Inorganic Chemistry 1989, 37: 99-142. DOI: 10.1002/9780470166383.ch2.Peer-Reviewed Original Research
1987
The tetranuclear manganese complex of Photosystem II
Brudvig G. The tetranuclear manganese complex of Photosystem II. Journal Of Bioenergetics And Biomembranes 1987, 19: 91-104. PMID: 3034873, DOI: 10.1007/bf00762719.Peer-Reviewed Original ResearchConceptsManganese complexesElectron paramagnetic resonance (EPR) spectroscopic studiesManganese ionsS2 stateTetranuclear manganese complexPhotosystem IIFour-electron oxidationIntermediate oxidation statesDisplacement of O2Coordination chemistryOxidation stateO bondSpectroscopic studiesS4 stateMagnetic propertiesComplexesIonsLike structureManganeseMn4O4ChemistryStructureBondsOxidationProperties