Kinetic analysis of the O2-forming reaction between [Mn(III)(dpa)2]− (dpa=dipicolinate) and potassium peroxomonosulfate
Limburg J, Crabtree* R, Brudvig* G. Kinetic analysis of the O2-forming reaction between [Mn(III)(dpa)2]− (dpa=dipicolinate) and potassium peroxomonosulfate. Inorganica Chimica Acta 2000, 297: 301-306. DOI: 10.1016/s0020-1693(99)00362-x.Peer-Reviewed Original ResearchO2-evolving complexPotassium peroxomonosulfateO2 evolutionComplexes of formulaO2-evolving reactionsFour-electron oxidationPhotosynthetic water oxidationPhotosystem IITerpy complexesWater oxidationManganese complexesKinetic analysisSide reactionsBond formationMolecular oxygenOxygen atomsReactionComplexesPeroxomonosulfateKey stepOxidationKobsManganeseTerpyridineTerpy