2023
Selective Methane Oxidation by Heterogenized Iridium Catalysts
Li H, Fei M, Troiano J, Ma L, Yan X, Tieu P, Yuan Y, Zhang Y, Liu T, Pan X, Brudvig G, Wang D. Selective Methane Oxidation by Heterogenized Iridium Catalysts. Journal Of The American Chemical Society 2023, 145: 769-773. PMID: 36594824, DOI: 10.1021/jacs.2c09434.Peer-Reviewed Original ResearchConceptsSelective methane oxidationValue-added oxygenatesPrepared catalystIr complexesIr centerOxide supportIridium catalystEasy separationC bondDirect CHImmobilization approachCatalystMethyl migrationOH productionMethane oxidationAcetic acidDirect routeKey stepCHCarbonylationElectrophilicityOxygenatesCarbonylBondsOxidation
2018
Some crystal growth strategies for diffraction structure studies of iridium complexes
Sharninghausen L, Sinha S, Shopov D, Brudvig G, Crabtree R. Some crystal growth strategies for diffraction structure studies of iridium complexes. Inorganica Chimica Acta 2018, 480: 183-188. DOI: 10.1016/j.ica.2018.05.017.Peer-Reviewed Original ResearchHydrogen bonding groupsHigher oxidation statesCrystal growth strategiesLarge enough crystalsCluster anionsIr complexesCluster cationsIridium complexesHydrogen bondingOxidation stateStandard crystallization methodsGel methodBonding groupsEnough crystalsCrystallization methodStructure studiesComplexesNeutron diffractionAnionsCationsHydrideBondingDiolDiffractionButane