2013
Cp* Iridium Precatalysts for Selective C–H Oxidation with Sodium Periodate As the Terminal Oxidant
Zhou M, Hintermair U, Hashiguchi B, Parent A, Hashmi S, Elimelech M, Periana R, Brudvig G, Crabtree R. Cp* Iridium Precatalysts for Selective C–H Oxidation with Sodium Periodate As the Terminal Oxidant. Organometallics 2013, 32: 957-965. DOI: 10.1021/om301252w.Peer-Reviewed Original ResearchH oxidationTerminal oxidantTime-resolved dynamic light scatteringSodium periodateEfficient terminal oxidantH bond cleavageMetal oxide nanoparticlesDynamic light scatteringFunctional group toleranceKinetic isotope effectsMethylene oxidationRetention of configurationCyclohexane oxidationWater oxidationIridium precatalystBond cleavageSulfonate groupsHomogeneous pathwayH bondsGroup toleranceNatural productsOxide nanoparticlesLight scatteringOxidationUseful yields
2006
Molecular Recognition in the Selective Oxygenation of Saturated C-H Bonds by a Dimanganese Catalyst
Das S, Incarvito CD, Crabtree RH, Brudvig GW. Molecular Recognition in the Selective Oxygenation of Saturated C-H Bonds by a Dimanganese Catalyst. Science 2006, 312: 1941-1943. PMID: 16809537, DOI: 10.1126/science.1127899.Peer-Reviewed Original ResearchConceptsHydrogen bondingMolecular recognitionH bondsCarboxylic acid groupsMolecular recognition elementsSynthetic catalystsSaturated CKemp's triacidSelective oxygenationCOOH groupRegioselective functionalizationH activationHigh selectivityAcid groupsRecognition groupReactive centerRecognition elementCatalystTriacidOrient substratesSelectivityBondingBondsControl experimentsSubstrate